Radiation Vulcanization of EPDM Rubber with Polyfunctional Monomers
نویسندگان
چکیده
منابع مشابه
Vulcanization and the Properties of Rubber
Rubber is composed of long stringlike polymer molecules, which are pinned together at random points by crosslinks. As the density of crosslinks is increased, the molecules get localized and the system undergoes a phase transition from a liquid to an amorphous solid state. The elastic properties of the resulting solid are very different from those of metals, and are primarily due to changes in t...
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Dynamic compressive stress-strain curves at various strain rates of an EthylenePropylene-Diene Monomer Copolymer (EPDM) rubber have been determined with a modified split Hopkinson pressure bar (SHPB). The use of a pulse-shaping technique ensures that the specimen deforms at a nearly constant strain rate under dynamically equilibrated stress. The validity of the experiments was monitored by a hi...
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– A Landau theory is constructed for the vulcanization transition in cross-linked polymer systems with spontaneous nematic ordering. The neo-classical theory of the elasticity of nematic elastomers is derived via the minimization of this Landau free energy; this neoclassical theory contains the classical theory of rubber elasticity as its isotropic limit. Our work not only reveals the statistic...
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Two silane coupling agents were used for hydrolysis-condensation reaction modification of nanosilica surfaces. The surface characteristics were analyzed using Fourier transform infrared spectroscopy (FTIR). The vulcanization kinetics of natural rubber (NR) + silica composites was studied and compared to behavior of the neat NR using differential scanning calorimetry (DSC) in the dynamic scan mo...
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We previously reported that the dispersed rubber microparticles in ethylene-propylenediene monomer (EPDM)/polypropylene (PP) thermoplastic vulcanizates (TPVs) are actually agglomerates of rubber nanoparticles. In this study, based on this new understanding of the microstructure of TPV, we further revealed the microstructure-properties relationship of EPDM/PP TPV during dynamic vulcanization, es...
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ژورنال
عنوان ژورنال: Acta Physica Polonica A
سال: 2019
ISSN: 1898-794X,0587-4246
DOI: 10.12693/aphyspola.135.1061